Product ID:SUN PH MINUS, CPE710070
MSDS Date:02/28/1990
FSC:6850
NIIN:00N048893
MSDS Number: BVHTK

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

DISPOSAL GUIDELINES. MATL MAY BE NEUT FOR DISPOSAL;

RTECS: 9999999ZZ

FROM USE OF MATL. USER OF MATL HAS

RTECS: 9999999ZZ

I/A/W ALL RELEVANT LOCAL, STATE & FED LAWS & REGS

RTECS: 9999999ZZ

SODIUM BISULFATE

CAS: 7681-38-1

RTECS: VZ1860000

Fraction By Weight: 90-95%

OSHA PEL N/K

ACGIH TLV: N/K

1)

CAS: 7757-82-6

RTECS: WE1650000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

BRTHG HAS STOPPED, ARTF RESP SHOULD BE GIVEN IMMED.

BEFORE PERSON RETURNS TO WORK.

RTECS: 9999999ZZ

MATL IS HVR/WATER & IS

RTECS: 9999999ZZ

CLEANED UP AS SOON AS POSSIBLE & PLACED IN SEPARATE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 0.5-1.0 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: IRRITATION &/OR BURNS MAY
RESULT TO THROAT, UPPER RESPIRATORY TRACT & LUNGS. DAMAGE TO LUNGS
MAY RESULT. EYES: CONTACT WOULD BE EXPECTED TO CAUSE IRRITATION
CONSISTING OF REDNESS, SWELLING & MU COUS DISCHARGE TO CONJUNCTIVA.
IF NOT WASHED QUICKLY FROM EYES, CORNEAL DAMAGE & VISUAL IMPAIRMENT
MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OCCUR. SKIN: MAY CAUSE IRRITATION
&/OR BURNS. INGEST: GASTROENTERITIS MAY OCCUR WITH NAUSEA,
VOMITING, LETHARGY & DIARRHEA. ULCERATION MAY ALSO OCCUR RESULTING
IN GI BLEEDING.
Medical Cond Aggravated by Exposure:ASTHMA MAY BE AGGRAVATED BY
EXPOSURE.

First Aid:EYES: IMMMED FLUSH W/LG AMTS WATER FOR @ LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER EYELIDS. CALL MD AT ONCE. SKIN: IMMED FLUSH
W/WATER FOR 15 MIN. WASH CONTAMD SKIN W/SOAP & WATER. IF IRRIT
DEVELOPS, CALL MD. IF CLTHG COMES IN CNTCT W/PROD, REMOVE IMMED &
LAUNDER BEFORE REUSE. INGEST: IMMED DRINK WATER TO DILUTE. INDUCE
VOMIT. CALL MD AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF PERSON
UNCON (SUPDAT)

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
. USE WATER TO COOL CNTNRS EXPOSED TO FIRE. MAY USE OTHER EXTING
AGENTS SUITABLE FOR SURROUNDING MATLS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:HAZ CONC IN AIR MAY BE FOUND IN LOCAL SPILL
AREA. PROD BECOMES CORR IRRIT UPON CNTCT W/SM AMT MOISTURE SUCH AS
PRESENT ON SKIN/EYES. IF PROD HEATED TO DECOMP, PRDCE SULFUR
DIOXIDES & SODIUM OXIDE. AIR RELS: VAPS MAY BE SUPRESSED BY USE OF
(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY AREA. KEEP AWAY
FROM MOISTURE. DO NOT STORE AT TEMP ABOVE 347F(175C). KEEP AWAY
FROM HIGH HUMIDITY, HIGH HEAT & ALKALINE MATLS.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES
OR CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER.
SHELF LIFE UNLIMITED IF STORED AS RECOMMENDED.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED HIGH EFFICIENCY
PARTICULATE (HEPA) FILTER RESPIRATOR.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MAINTAIN DUST LEVELS TO
BELOW THE TLV.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOG (WORK HYGIENE)
Other Protective Equipment:EMER EYEWASH & DELUGE SHOWR MEETING ANSI
DESIGN STD. WEAR GLOVE, BOOT, APRON/IMPERMEABLE SUIT TO AVOID SKIN
CNTCT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. EYE PROTECTION:
WITH FULL LENGTH FACESHIELD .
Supplemental Safety and Health
BP: DECOMPOSES @ 350F,176C. FIRST AID PROC: OR HAVING CONVLS. INHAL: IF
EXPERIENCE NAUS, HDCH/DIZZ, STOP WORK IMMED & MOVE TO FRESH AIR
UNTIL SYMP DISAPPER. IF BRTHG DFCLT, ADMIN OXYGEN, KEEP WARM & A T
REST. CALL MD. IF PERSON LOOSES CONSCIOUSNESS, MOVE TO FRESH AIR AT
ONCE & MD SHOULD BE CALLED IMMED. IF (ING 4)

HCC:N1
Boiling Pt:B.P. Text:SUPDAT
Melt/Freeze Pt:M.P/F.P Text:349F,176C
Spec Gravity:2.74
pH:SUPDAT
Solubility in Water:APPROXIMATELY 33%
Appearance and Odor:OFF-WHITE TO YELLOW GRANULAR BEADS; NO ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS, ALKALIES, OXIDIZERS.
Stability Condition to Avoid:TEMPERATURES ABOVE 570F, 315C. AVOID HIGH
HUMIDITY AND HIGH HEAT.
Hazardous Decomposition Products:SULFUR DIOXIDE, SULFUR TRIOXIDE,
HYDROGEN SULFIDE, SODIUM OXIDE IF HEATED OVER 570F.

Waste Disposal Methods:PROD IS HAZ WASTE UNDER 40 CFR 261 & HAS EPA HAZ
WASTE NUMBER: D002. IT MUST BE DISPOSED OF I/A/W LOCAL, STATE & FED
REGS IN PERMITTED HAZ WASTE TREATMENT, STORAGE & DISPOSAL FACILITY
BY TREATMENT. CA RE MUST BE TAKEN TO PVNT ENVIRON CONTAM(ING 9)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.